I. J. S. Fairlamb

In-Silico Prediction of Pd_Catalyzed Cross-Coupling Processes: Dibenzylidene Acetone (dba) Ligand Control (2007)

Fairlamb, I.J.S., Lee, A.F.

DFT calculations allow us to predict the electronic properties of dba-n,n‘-Z ligands and thereby control the reactivity of their corresponding Pd0 complexes in Suzuki−Miyaura, α-arylation, and...

Phosphinite Ligand Effects in Palladium(II)-Catalysed Cycloisomerisation of 1,6-Dienes: Bicyclo[3.2.0]heptanyl Diphosphinite (B[3.2.0]DPO) Ligands Exhibit Flexible Bite Angles, an Effect Derived from Conformational Changes (exo- or endo-Envelope) in the Bicyclic Ligand Scaffold (2006)

Fairlamb, I.J.S., Grant, S., Tommasi, S., Lynam, J.M., Bandini, M., Dong, H., ...

Changes in bidentate ligand structure significantly affect catalytic activity in mono-cationic Pd(II)-catalysed 1,6-diene cycloisomerisation processes to give cyclopentene products. A...

Sonogashira alkynylation of unprotected 8-brominated adenosines and guanosines: Fluorescence properties of compact conjugated acetylenes containing a purine ring (2006)

Firth, A.G., Fairlamb, I.J.S., Darley, K., Baumann, C.G.

A practical Sonogashira alkynylation protocol for the preparation of 8-alkynylated adenosines and guanosines has been developed. Protection of the sugar hydroxyl substituents is not required;...

Air stable, phosphine-free anionic palladacyclopentadienyl catalysts: Remarkable halide and pseudohalide effects in Stille coupling (2006)

Crawforth, C.M., Fairlamb, I.J.S., Kapdi, A.R., Serrano, J.L., Taylor, R.J.K., Sanchez, G.

The Stille cross-coupling of allylic and benzyl bromides is shown to proceed efficiently using phosphine-free dinuclear anionic palladacyclopentadienyl catalysts possessing bridging (N,O)-imidate...

Oxidative addition of N-halosuccinimides to palladium(0): The discovery of neutral palladium(II) imidate ligands, which enhance Stille coupling of allylic and benzylic halides (2005)

Crawforth, C.M., Burling, S., Fairlamb, I.J.S., Kapdi, A.R., Taylor, R.J.K., Whitwood, A.C.

The Stille coupling of organostannanes and organohalides, mediated by air and moisture stable palladium(II) phosphine complexes containing succinimide or phthalimide (imidate) ligands, has been...

n^1-bound 2-pyrone complexes of molybdenum and iron: a synthetic and structural study (2004)

Fairlamb, I.J.S., Lynam, J.M., Taylor, I.E., Whitwood, A.C.

n2-dba complexes of Pd(0): The substituent effect in Suzuki-Miyaura coupling (2004)

Fairlamb, I.J.S., Kapdi, A.R., Lee, A.F.

The influence of aryl substituents in dibenzylidene acetone (dba) ligands, for Pd(0) complexes, has been evaluated for Suzuki−Miyaura cross-coupling reactions. Electron-withdrawing substituents...