Suse Broyde

Influence of local sequence context on damaged base conformation in human DNA polymerase {iota}: molecular dynamics studies of nucleotide incorporation opposite a benzo[a]pyrene-derived adenine lesion (2009)

Donny-Clark, Kerry, Broyde, Suse

Human DNA polymerase &igr; is a lesion bypass polymerase of the Y family, capable of incorporating nucleotides opposite a variety of lesions in both near error-free and error-prone bypass. With...

Transcription elongation past O6-methylguanine by human RNA polymerase II and bacteriophage T7 RNA polymerase (2008)

Dimitri, Alexandra, Burns, John A., Broyde, Suse, Scicchitano, David A.

O6-Methylguanine (O6-meG) is a major mutagenic, carcinogenic and cytotoxic DNA adduct produced by various endogenous and exogenous methylating agents. We report the results of transcription past a...

The N-clasp of human DNA polymerase {kappa} promotes blockage or error-free bypass of adenine- or guanine-benzo[a]pyrenyl lesions (2008)

Jia, Lei, Geacintov, Nicholas E., Broyde, Suse

DNA bypass polymerases are utilized to transit bulky DNA lesions during replication, but the process frequently causes mutations. The structural origins of mutagenic versus high fidelity replication...

Following an environmental carcinogen N2-dG adduct through replication: elucidating blockage and bypass in a high-fidelity DNA polymerase (2007)

Xu, Pingna, Oum, Lida, Beese, Lorena S., Geacintov, Nicholas E., Broyde, Suse

We have investigated how a benzo[a]pyrene-derived N2-dG adduct, 10S(+)-trans-anti-[BP]-N2-dG ([BP]G*), is processed in a well-characterized Pol I family model replicative DNA polymerase, Bacillus...

Exocyclic amino groups of flanking guanines govern sequence-dependent adduct conformations and local structural distortions for minor groove-aligned benzo[a]pyrenyl-guanine lesions in a GG mutation hotspot context (2007)

Rodríguez, Fabián A., Cai, Yuqin, Lin, Chin, Tang, Yijin, Kolbanovskiy, Alexander, Amin, Shantu, ...

The environmental carcinogen benzo[a]pyrene (BP) is metabolized to reactive diol epoxides that bind to cellular DNA by predominantly forming N2-guanine adducts (G*). Mutation hotspots for these...

Exocyclic amino groups of flanking guanines govern sequence-dependent adduct conformations and local structural distortions for minor groove-aligned benzo[a]pyrenyl-guanine lesions in a GG mutation hotspot context (2007)

Rodríguez, Fabián A., Cai, Yuqin, Lin, Chin, Tang, Yijin, Kolbanovskiy, Alexander, Amin, Shantu, ...

The environmental carcinogen benzo[a]pyrene (BP) is metabolized to reactive diol epoxides that bind to cellular DNA by predominantly forming N2-guanine adducts (G*). Mutation hotspots for these...

Exocyclic amino groups of flanking guanines govern sequence-dependent adduct conformations and local structural distortions for minor groove-aligned benzo[a]pyrenyl-guanine lesions in a GG mutation hotspot context (2007)

Rodríguez, Fabián A., Cai, Yuqin, Lin, Chin, Tang, Yijin, Kolbanovskiy, Alexander, Amin, Shantu, ...

The environmental carcinogen benzo[a]pyrene (BP) is metabolized to reactive diol epoxides that bind to cellular DNA by predominantly forming N2-guanine adducts (G*). Mutation hotspots for these...

Stepwise Translocation of Dpo4 Polymerase during Error-Free Bypass of an oxoG Lesion (2006)

Olga Rechkoblit, Lucy Malinina, Yuan Cheng, Vitaly Kuryavyi, Suse Broyde, Nicholas E. Geacintov, ...

Crystal structures of the bypass polymerase Dpo4 at different stages of lesion-bypass reveal how the cell copes with oxidative DNA damage.

Stepwise Translocation of Dpo4 Polymerase during Error-Free Bypass of an oxoG Lesion (2006)

Olga Rechkoblit, Lucy Malinina, Yuan Cheng, Vitaly Kuryavyi, Suse Broyde, Nicholas E. Geacintov, ...

7,8-dihydro-8-oxoguanine (oxoG), the predominant lesion formed following oxidative damage of DNA by reactive oxygen species, is processed differently by replicative and bypass polymerases. Our...

Mutagenic nucleotide incorporation and hindered translocation by a food carcinogen C8-dG adduct in Sulfolobus solfataricus P2 DNA polymerase IV (Dpo4): modeling and dynamics studies (2006)

Zhang, Ling, Rechkoblit, Olga, Wang, Lihua, Patel, Dinshaw J., Shapiro, Robert, Broyde, Suse

Bulky carcinogen-DNA adducts commonly cause replicative polymerases to stall, leading to a switch to bypass polymerases. We have investigated nucleotide incorporation opposite the major adduct of...

A new anti conformation for N-(deoxyguanosin-8-yl)-2-acetylaminofluorene (AAF-dG) allows Watson-Crick pairing in the Sulfolobus solfataricus P2 DNA polymerase IV (Dpo4) (2006)

Wang, Lihua, Broyde, Suse

Primer extension studies have shown that the Y-family DNA polymerase IV (Dpo4) from Sulfolobus solfataricus P2 can preferentially insert C opposite N-(deoxyguanosin-8-yl)-2-acetylaminofluorene...

10.1098/rsta.2004.1386 Deformations of promoter DNA bound to (2004)

Qing Zhang, Suse Broyde, Tamar Schlick

carcinogens help interpret effects on TATA-element structure and activity

Human RNA polymerase II is partially blocked by DNA adducts derived from tumorigenic benzo[c]phenanthrene diol epoxides: relating biological consequences to conformational preferences (2003)

Schinecker, Thomas M., Perlow, Rebecca A., Broyde, Suse, Geacintov, Nicholas E., Scicchitano, David A.

Environmental polycyclic aromatic hydrocarbons (PAHs) are metabolically activated to diol epoxides that can react with DNA, resulting in covalent modifications to the bases. The (+)‐ and...

Relating repair susceptibility of carcinogen-damaged DNA with structural distortion and thermodynamic stability (2002)

Wu, Min, Yan, Shixiang, Patel, Dinshaw J., Geacintov, Nicholas E., Broyde, Suse

A key issue in the nucleotide excision repair (NER) of bulky carcinogen–DNA adducts is the ability of the NER machinery to recognize and repair certain adducts while failing to repair others....

Solution properties and computational analysis of an oligodeoxynucleotide containing N-(deoxyguanosin-8-yl)-1-aminopyrene (1996)

Nolan, Scott J., Vyas, Rajeev R., Hingerty, Brian E., Ellis, Stephen, Broyde, Suse, Shapiro, Robert, ...

An oligodeoxyribonucleotide 5' -d(CTCATGAPATTCC), in which GAP denotes N-(guanin-8-yl)-1-aminopyrene, the C8-guanine adduct of reductively activated 1-nitropyrene, was synthesized and characterized...

Visualization of an AAF induced frameshift mutation: molecular views of base displacement in B-DNA from minimized potential energy calculations (1987)

Broyde, Suse, Hingerty, Brian E.

Energy minimized structures of base displacement in an AAF modified B-DNA dodecamer are presented. A rational search strategy, beginning with a global search of the conformation space of the modified...

Studies on the conformation and dynamics of the C8-substituted guanlne adduct of the carcinogen acetytaminofluorene; model for a possible Z-DNA modified structure (1984)

Neidle, Stephen, Kuroda, Reiko, Broyde, Suse, Hingerty, Brian E., Levine, Robert A., Miller, Dwight W., ...

The structure of an adduct between guanine and the carcinogen acetylaminofluorene has been examined in the solid state by X-ray crystallography, and in solution by NMR techniques. The observed...

Z-DNA conformation of N-2-acetylaminofluorene modified poly(dG-dC){middle dot}poly(dG-dC) determined by reactivity with anti cytidine antibodies and minimized potential energy calculations (1981)

Santella, Regina M., Grunberger, Dezider, Broyde, Suse, Hingerty, Brian E.

The conformation of poly(dG-dC)·poly(dG-dC), poly(dG)·poly(dC), and calf thymus DNA modified with N-acetoxy-N-2-acetylaminofluorene (N-acetoxy-AAF) was examined by extent of reaction with anti...

Solution structure of the 2-amino-1- methyl-6-phenylimidazo[4,5-b]pyridine C8-deoxyguanosine adduct in duplex DNA

Brown, Karen, Hingerty, Brian E., Guenther, Elizabeth A., Krishnan, V. V., Broyde, Suse, Turteltaub, Kenneth W., ...

The carcinogenic heterocyclic amine (HA) 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PhIP) is formed during the cooking of various meats. To enable structure/activity studies aimed at...

Relating repair susceptibility of carcinogen-damaged DNA with structural distortion and thermodynamic stability

Wu, Min, Yan, Shixiang, Patel, Dinshaw J., Geacintov, Nicholas E., Broyde, Suse

A key issue in the nucleotide excision repair (NER) of bulky carcinogen–DNA adducts is the ability of the NER machinery to recognize and repair certain adducts while failing to repair others....

Human RNA polymerase II is partially blocked by DNA adducts derived from tumorigenic benzo[c]phenanthrene diol epoxides: relating biological consequences to conformational preferences

Schinecker, Thomas M., Perlow, Rebecca A., Broyde, Suse, Geacintov, Nicholas E., Scicchitano, David A.

Environmental polycyclic aromatic hydrocarbons (PAHs) are metabolically activated to diol epoxides that can react with DNA, resulting in covalent modifications to the bases. The (+)- and...

Accurate representation of B-DNA double helical structure with implicit solvent and counterions.

Wang, Lihua, Hingerty, Brian E, Srinivasan, A R, Olson, Wilma K, Broyde, Suse

High-resolution nuclear magnetic resonance (NMR) and crystallographic data have been taken to refine the force field used in the torsion angle space nucleic acids molecular mechanics program DUPLEX....

Simulating Structural and Thermodynamic Properties of Carcinogen-Damaged DNA

Yan, Shixiang, Wu, Min, Patel, Dinshaw J., Geacintov, Nicholas E., Broyde, Suse

A pair of stereoisomeric covalent adducts to guanine in double-stranded DNA, derived from the reaction of mutagenic and tumorigenic metabolites of benzo[a]pyrene, have been well characterized...

Highly Organized but Pliant Active Site of DNA Polymerase β: Compensatory Mechanisms in Mutant Enzymes Revealed by Dynamics Simulations and Energy Analyses

Yang, Linjing, Beard, William A., Wilson, Samuel H., Broyde, Suse, Schlick, Tamar

To link conformational transitions noted for DNA polymerases with kinetic results describing catalytic efficiency and fidelity, we investigate the role of key DNA polymerase β residues on subdomain...

Stepwise Translocation of Dpo4 Polymerase during Error-Free Bypass of an oxoG Lesion

Rechkoblit, Olga, Malinina, Lucy, Cheng, Yuan, Kuryavyi, Vitaly, Broyde, Suse, Geacintov, Nicholas E, ...

7,8-dihydro-8-oxoguanine (oxoG), the predominant lesion formed following oxidative damage of DNA by reactive oxygen species, is processed differently by replicative and bypass polymerases. Our...

A new anti conformation for N-(deoxyguanosin-8-yl)-2-acetylaminofluorene (AAF-dG) allows Watson–Crick pairing in the Sulfolobus solfataricus P2 DNA polymerase IV (Dpo4)

Wang, Lihua, Broyde, Suse

Primer extension studies have shown that the Y-family DNA polymerase IV (Dpo4) from Sulfolobus solfataricus P2 can preferentially insert C opposite N-(deoxyguanosin-8-yl)-2-acetylaminofluorene...

Mutagenic nucleotide incorporation and hindered translocation by a food carcinogen C8-dG adduct in Sulfolobus solfataricus P2 DNA polymerase IV (Dpo4): modeling and dynamics studies

Zhang, Ling, Rechkoblit, Olga, Wang, Lihua, Patel, Dinshaw J., Shapiro, Robert, Broyde, Suse

Bulky carcinogen-DNA adducts commonly cause replicative polymerases to stall, leading to a switch to bypass polymerases. We have investigated nucleotide incorporation opposite the major adduct of...

Solution structure of the 2-amino-1- methyl-6-phenylimidazo[4,5-b]pyridine C8-deoxyguanosine adduct in duplex DNA

Brown, Karen, Hingerty, Brian E., Guenther, Elizabeth A., Krishnan, V. V., Broyde, Suse, Turteltaub, Kenneth W., ...

The carcinogenic heterocyclic amine (HA) 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PhIP) is formed during the cooking of various meats. To enable structure/activity studies aimed at...

Relating repair susceptibility of carcinogen-damaged DNA with structural distortion and thermodynamic stability

Wu, Min, Yan, Shixiang, Patel, Dinshaw J., Geacintov, Nicholas E., Broyde, Suse

A key issue in the nucleotide excision repair (NER) of bulky carcinogen–DNA adducts is the ability of the NER machinery to recognize and repair certain adducts while failing to repair others....

Human RNA polymerase II is partially blocked by DNA adducts derived from tumorigenic benzo[c]phenanthrene diol epoxides: relating biological consequences to conformational preferences

Schinecker, Thomas M., Perlow, Rebecca A., Broyde, Suse, Geacintov, Nicholas E., Scicchitano, David A.

Environmental polycyclic aromatic hydrocarbons (PAHs) are metabolically activated to diol epoxides that can react with DNA, resulting in covalent modifications to the bases. The (+)- and...

Accurate representation of B-DNA double helical structure with implicit solvent and counterions.

Wang, Lihua, Hingerty, Brian E, Srinivasan, A R, Olson, Wilma K, Broyde, Suse

High-resolution nuclear magnetic resonance (NMR) and crystallographic data have been taken to refine the force field used in the torsion angle space nucleic acids molecular mechanics program DUPLEX....

Simulating Structural and Thermodynamic Properties of Carcinogen-Damaged DNA

Yan, Shixiang, Wu, Min, Patel, Dinshaw J., Geacintov, Nicholas E., Broyde, Suse

A pair of stereoisomeric covalent adducts to guanine in double-stranded DNA, derived from the reaction of mutagenic and tumorigenic metabolites of benzo[a]pyrene, have been well characterized...

Highly Organized but Pliant Active Site of DNA Polymerase β: Compensatory Mechanisms in Mutant Enzymes Revealed by Dynamics Simulations and Energy Analyses

Yang, Linjing, Beard, William A., Wilson, Samuel H., Broyde, Suse, Schlick, Tamar

To link conformational transitions noted for DNA polymerases with kinetic results describing catalytic efficiency and fidelity, we investigate the role of key DNA polymerase β residues on subdomain...

Stepwise Translocation of Dpo4 Polymerase during Error-Free Bypass of an oxoG Lesion

Rechkoblit, Olga, Malinina, Lucy, Cheng, Yuan, Kuryavyi, Vitaly, Broyde, Suse, Geacintov, Nicholas E, ...

7,8-dihydro-8-oxoguanine (oxoG), the predominant lesion formed following oxidative damage of DNA by reactive oxygen species, is processed differently by replicative and bypass polymerases. Our...

A new anti conformation for N-(deoxyguanosin-8-yl)-2-acetylaminofluorene (AAF-dG) allows Watson–Crick pairing in the Sulfolobus solfataricus P2 DNA polymerase IV (Dpo4)

Wang, Lihua, Broyde, Suse

Primer extension studies have shown that the Y-family DNA polymerase IV (Dpo4) from Sulfolobus solfataricus P2 can preferentially insert C opposite N-(deoxyguanosin-8-yl)-2-acetylaminofluorene...

Mutagenic nucleotide incorporation and hindered translocation by a food carcinogen C8-dG adduct in Sulfolobus solfataricus P2 DNA polymerase IV (Dpo4): modeling and dynamics studies

Zhang, Ling, Rechkoblit, Olga, Wang, Lihua, Patel, Dinshaw J., Shapiro, Robert, Broyde, Suse

Bulky carcinogen-DNA adducts commonly cause replicative polymerases to stall, leading to a switch to bypass polymerases. We have investigated nucleotide incorporation opposite the major adduct of...

Exocyclic amino groups of flanking guanines govern sequence-dependent adduct conformations and local structural distortions for minor groove-aligned benzo[a]pyrenyl-guanine lesions in a GG mutation hotspot context

Rodríguez, Fabián A., Cai, Yuqin, Lin, Chin, Tang, Yijin, Kolbanovskiy, Alexander, Amin, Shantu, ...

The environmental carcinogen benzo[a]pyrene (BP) is metabolized to reactive diol epoxides that bind to cellular DNA by predominantly forming N2-guanine adducts (G*). Mutation hotspots for these...

Following an environmental carcinogen N2-dG adduct through replication: elucidating blockage and bypass in a high-fidelity DNA polymerase

Xu, Pingna, Oum, Lida, Beese, Lorena S., Geacintov, Nicholas E., Broyde, Suse

We have investigated how a benzo[a]pyrene-derived N2-dG adduct, 10S(+)-trans-anti-[BP]-N2-dG ([BP]G*), is processed in a well-characterized Pol I family model replicative DNA polymerase, Bacillus...

The human DNA repair factor XPC-HR23B distinguishes stereoisomeric benzo[a]pyrenyl-DNA lesions

Mocquet, Vincent, Kropachev, Konstantin, Kolbanovskiy, Marina, Kolbanovskiy, Alexander, Tapias, Angels, Cai, Yuqin, ...

Benzo[a]pyrene (B[a]P), a known environmental pollutant and tobacco smoke carcinogen, is metabolically activated to highly tumorigenic B[a]P diol epoxide derivatives that predominantly form...

Transcription elongation past O6-methylguanine by human RNA polymerase II and bacteriophage T7 RNA polymerase

Dimitri, Alexandra, Burns, John A., Broyde, Suse, Scicchitano, David A.

O6-Methylguanine (O6-meG) is a major mutagenic, carcinogenic and cytotoxic DNA adduct produced by various endogenous and exogenous methylating agents. We report the results of transcription past a...

The N-clasp of human DNA polymerase κ promotes blockage or error-free bypass of adenine- or guanine-benzo[a]pyrenyl lesions

Jia, Lei, Geacintov, Nicholas E., Broyde, Suse

DNA bypass polymerases are utilized to transit bulky DNA lesions during replication, but the process frequently causes mutations. The structural origins of mutagenic versus high fidelity replication...

Influence of local sequence context on damaged base conformation in human DNA polymerase ι: molecular dynamics studies of nucleotide incorporation opposite a benzo[a]pyrene-derived adenine lesion

Donny-Clark, Kerry, Broyde, Suse

Human DNA polymerase ι is a lesion bypass polymerase of the Y family, capable of incorporating nucleotides opposite a variety of lesions in both near error-free and error-prone bypass. With...